无机化学

李德慧

目录

  • 1 第一章  绪论
    • 1.1 化学研究的对象
    • 1.2 无机化学的发展历史
    • 1.3 无机化学与药学
    • 1.4 无机化学的内容与学习方法
  • 2 第二章  溶液
    • 2.1 溶液浓度的表示法
  • 3 第三章  化学平衡
    • 3.1 化学反应的可逆性
    • 3.2 化学平衡的移动
  • 4 第四章  酸碱平衡
    • 4.1 酸碱理论的发展
    • 4.2 弱电解质的质子传递平衡
    • 4.3 缓冲溶液
    • 4.4 英语总结
  • 5 第五章  沉淀-溶解平衡
    • 5.1 溶度积原理
    • 5.2 沉淀的生成与溶解
    • 5.3 英语总结
  • 6 第六章  氧化还原反应
    • 6.1 氧化还原反应
    • 6.2 电极电势
    • 6.3 电极电势的影响因素
    • 6.4 电极电势的应用
    • 6.5 英语总结
  • 7 第七章  原子结构
    • 7.1 原子的结构
    • 7.2 核外电子运动的特征
    • 7.3 氢原子结构的量子力学模型
    • 7.4 多电子原子的结构
    • 7.5 元素周期表
    • 7.6 元素性质的周期性
    • 7.7 英语总结
    • 7.8 双语习题
  • 8 第八章  分子结构与化学键
    • 8.1 离子键
    • 8.2 共价键
    • 8.3 分子的极性
    • 8.4 分子间作用力和氢键
    • 8.5 英语总结
    • 8.6 双语习题
  • 9 配位化合物
    • 9.1 配合物的基本概念
    • 9.2 配合物的化学键理论
    • 9.3 配位平衡的移动
    • 9.4 配位化合物的应用
    • 9.5 英语总结
英语总结

Summary

The quantum theory is necessary to describes electrons. It predicts discrete allowed levels  and wavefunctions, which give probably distributions tor electrons. Wavefunctions for elec trons in atomic orbitals.

Atomic orbitals are labeled by 3 quantum numbers n ,i and m , Orbitals are called s,p,d or f according the value of i ; there are respectively 1 ,3,5 and 7 different possible m values for these orbitals.

Electrons have an intrinsic rotation called spin, which may point in only 2 possible directions, specified by a quantum number s just as a value of + 1 /2 or - 1/2. Two electrons in the same orbital with opposite spin are paired.

The radial distribution function shows how far from the nucleus an electron is likely to be found. The major features depend on n but there is some dependence on 1 . The allowed energy in hydrogen depend on n only. And the angular distribution function shows how it varies with the direction in space.

When the spin quantum number s is included, no two electrons in an atom may have the same set of quantum numbers.Thus the maximum number of electrons in any orbital is two.

The electronic repulsion between electrons weakens their binding in an atom. This is known as screening or shielding. An orbital is screened more effectively if its radial distribution does not penetrate those of other the lowest energy state is formed by putting electrons as far as electrons,When filling orbitals with I>0, the lowest energy state is formed by putting electrons as far as possible in orbitals with different m values, and with parallel spin , which according to the 3 principles of minimum energy principle,and and Hund's rule.

The periodic table shows elements arranged horizontally in periods and vertically in groups according to their chemical similarity .Elements in the same group have the same configuration of outer electrons. The table is divided naturally into s,p,d (ds) and f blocks according to the outer electron configurations. Electronegativity (electron-withdrawing or attraction power ) of the elements vary in a regular manner according to atomic number .

Many elements (macroelements and trace elements) are essential for biology; include their ability to display variable oxidation states and catalytic activity. And some of elements in the table are non-essential elements and even poisonous elements for biology.