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有机化学双语课程（Bilingual Organic Chemis...

赵新筠

1 Introduction
- 1.1 General information about organic chemistry
- 1.2 The nature of covalent bonds
- 1.3 Structures of molecules
- 1.4 Conjugative effects
- 1.5 Chemical reactions
- 1.6 PPT
- 1.7 Online test
- 1.8 literaures reading
2 Alkanes
- 2.1 Structures of Alkanes
- 2.2 Nomenclature of Alkanes
- 2.3 Isomerism of Alkanes
- 2.4 Properties of Alkanes
- 2.5 PPT
- 2.6 Online test
3 Cycloalkanes
- 3.1 Isomerism of cycloalkanes
- 3.2 Nomenclature of cycloalkanes
- 3.3 Chemical Properties of Cycloalkanes
- 3.4 Conformations of Cyclohexane
- 3.5 PPT
- 3.6 Online test
- 3.7 literatures reading
4 Stereochemistry
- 4.1 Stereoisomerism
- 4.2 Chirality
- 4.3 R, S naming system
- 4.4 Chirality in chemical reactions
- 4.5 PPT
- 4.6 Online test
- 4.7 literatures reading
5 Alkenes
- 5.1 Nomenclature of Alkenes
- 5.2 Isomerism of Alkenes
- 5.3 Chemical Reactions of Alkenes
  - 5.3.1 Addition of Hydrogen Halides to Alkenes and Carbocation Rearrangements
  - 5.3.2 Electrophilic Addition of Alkenes with H2O,HOR,H2SO4
  - 5.3.3 Halogenation
  - 5.3.4 Hydroboration-Oxidation of Alkenes
  - 5.3.5 Oxidation of Alkenes
  - 5.3.6 Hydrogenation of Alkenes
  - 5.3.7 Radical Addditon of HBr to Alkenes
  - 5.3.8 alpha-Hydrogen of Alkenes
- 5.4 Preparation of Alkenes
- 5.5 Dienes
- 5.6 Electrophilic addition reactions
- 5.7 Other reactions of alkenes
- 5.8 PPT
- 5.9 Online test
- 5.10 literatures reading
6 Alkynes
- 6.1 Nomenclature of Alkynes
- 6.2 Chemical Reactions of Alkynes
  - 6.2.1 Electrophilic Addition Reactions of Alkynes
  - 6.2.2 Oxidation Reactions of Alkynes
  - 6.2.3 Reduction Reactions of Alkynes
  - 6.2.4 Weak Acidity of Terminal Alkynes
- 6.3 Preparation of Alkynes
- 6.4 PPT
- 6.5 Online test
7 Organohalides
- 7.1 Structure, Classification and Nomenclature of Organohalides
- 7.2 Chemical Reactions
  - 7.2.1 Nucleophilic Substitution Reactions
  - 7.2.2 Elimination Reactions
  - 7.2.3 Other Chemical Reactions
- 7.3 Mechanisms of Nucleophilic substitution reactions
  - 7.3.1 SN2 Mechanism
  - 7.3.2 SN1 Mechanism
- 7.4 Mechanisms of Elimination Reactions
- 7.5 Competing reactions of substitution and elimination reactions
- 7.6 Preparation of Halohydrocarbons
- 7.7 PPT
- 7.8 Online test
- 7.9 literatures reading
8 Aromatic hydrocarbons
- 8.1 Aromatic compounds
- 8.2 Nomenclature of Benzene Derivatives
- 8.3 Electrophilic Substitution of Benzene
  - 8.3.1 Halogenation
  - 8.3.2 Nitration
  - 8.3.3 Sulfonation
  - 8.3.4 F-C alkylation and acylation
- 8.4 Substituent Effects
- 8.5 Reduction reactions
- 8.6 Side Chain Reactions of Alkylbenzene
- 8.7 Other Aromatic Compounds
- 8.8 Aromaticity
- 8.9 PPT
- 8.10 Online test
- 8.11 Literatures reading
9 Alcohols and Phenols
- 9.1 PPT
- 9.2 Summary of Reactions
  - 9.2.1 Reactions of alcohols
  - 9.2.2 Reactions of phenols
- 9.3 Synthesis of alcohols
- 9.4 Aspirin
- 9.5 literatures reading
- 9.6 Online test
10 Ethers
- 10.1 PPT
- 10.2 Summary of Reactions
- 10.3 Synthesis of ethers
- 10.4 Online test
11 Aldehydes and ketones
- 11.1 PPT
- 11.2 Summary of Reactions
- 11.3 Wolff-Kishner-Huang Minlon reaction
- 11.4 literatures reading
- 11.5 Online test
12 Carboxylic acids
- 12.1 PPT
- 12.2 Summary of Reactions
- 12.3 Preparation of carboxylic acids
- 12.4 Online test
13 Carboxylic acid derivatives
- 13.1 PPT
- 13.2 Summary of Reactions
- 13.3 Online test
14 Amines
- 14.1 PPT
- 14.2 Summary of Reactions
- 14.3 Preparation of amines
- 14.4 Toxicity of N-nitros amines
- 14.5 Online test
15 Heterocycle compounds
- 15.1 PPT
- 15.2 Online test

Side Chain Reactions of Alkylbenzene

8. Aromatic compounds

8.6 Side Chain Reactions of Alkylbenzene

In this section, you need to know the following information:

1) Oxidation reaction

Alkylside chains can be oxidized to -CO2H bystrong reagents such as KMnO4 and Na2Cr2O7 ifthey have a C–H next to the ring

2) Halogenation:

Stable benzylic radical intermediate

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