Unit 19 Hydration of Portland Cement
The silicates and aluminates present in cement react with water to form products of hydration and in time, these to a hard mass. The different anhydrous phases have very different cementitious properties, C3S hydrates rapidly and develops high early strength whereas β-C2S hardens more slowly. Hydration products of C3A and C4AF have very little strength. The hydration of commercial cement can be represented approximately by the summed hydration of the components. C3S is the phase mainly responsible for the initial hardening; C3S and β-C2S give set cement and concrete its long time strength.
Hydration of cement is a complicated process and part of the difficulty in studying it is that the main products of hydration are either gelatinous or poorly crystalline, thus making conventional X-ray diffraction studies extremely difficult.

